Curriculum Vitae (A. Yoshimura)

Business address

Department of Chemistry, Graduate School of Science, Osaka Metropolitan University

3-3-138 Sugimoto Sumiyoshi-ku, Osaka, 558-8585, Japan

TEL: +81-6-6605-3056

E-mail: yoshimura_aya@omu.ac.jp

Personal data

Born: 22 May 1982, Kyoto, Japan

Employment

2008-2012, DKS Co. Ltd.

Professional Career

April 2025 to present, Lecturer, Osaka Metropolitan University, Department of Chemistry, Graduate School of Science

April 2017 - March 2025, Assistant Professor, Ehime University, Department of Applied Chemistry, Graduate School of Science and Engineering

April 2015 - March 2017, Postdoctoral Fellow, The National Institute of Advanced Industrial Science and Technology (AIST), Interdisciplinary Research Center for Catalytic Chemistry

Award

Award of Grant for Collaborative Research Promoting Diversity, 2020

Thieme Chemistry Journals Award, 2024

Original Article

・34. 4D-Synthesis of [4]Dendralene Derivatives Possessing Quad-ruple 1,3-Dithiol-2-ylidenes and Transformation to a Tri-methylenecylopentene in an Oxidation State, Y. Kawasaki, D. Kasai, M. Ueda, M. Takezaki, A. Yoshimura, T. Shirahata, Y. Misaki, Org. Lett. 27, 2323-2327 (2025).

・33. The Synthesis of Unsymmetrical Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C-H Arylation, A. Yoshimura, Y. Aso, R. Utsumi, F. Tosa, Y. Misaki, Synlett 36, 859-863 (2025).

・32. Cation-Independent Anion Battery Using Organic Cathodes Utilizing a Triphenylamine Moiety for In-Cell Electropolymerization, H. Sano, A. Yoshimura, Z. Lei, H. Ebisawa, T. Kiyokawa, K. Fujita, Y. Misaki, M. Yao, ACS App. Polym. Mater. 6, 7542-7550 (2024).

・31. Synthesis and properties of 1,3-dithiole[6]dendralene analogs with two thiophene spacers inserted, T. Misaki, M. Nishiwaki, T. Ito, M. Ueda, A. Yoshimura, T. Shirahata, M. Hayashi, Y. Misaki, Chem. Lett. 53, upae104 (2024).

・30. Synthesis, Structures, and Electrochemical and Optical Properties of Vinyl-Extended Tetrathiafulvalene Functionalized Two 2,6-Dicyano-l⁵-Phosphinine Units, T. Misaki, A. Yoshimura, T. Shirahata, M. Hayashi, Y. Misaki, D. Sakamaki, H. Fujiwara, Eur. J. Org. Chem. 27, e202400088 (2024).

・29. Synthesis of Bz-TTFs with Polymerization Sites and Properties of Li-ion Batteries Comprising them as Active Materials, A. Yoshimura, M. Yoshinouchi, K. Hemmi, Y. Aso, R. Utsumi, T. Shirahata, M. Yao, Y. Misaki, New J. Chem. 47, 11760-11764 (2023).

・28. Synthesis, Structures and Redox Behavior of Methyl-subtituted Derivatives of Thiophene-inserted [3]Dendralene with Redox-active 1,3-Dithiol-2-ylidene Units, T. Ito, M. Ueda, M. Fujisaki, A. Yoshimura, T. Shirahata, Y. Misaki, Bull. Chem. Soc. Jpn. 95, 1419-1427 (2022).

・27. Improvement in Cycle Life of Organic Lithium-Ion Batteries by In-Cell Polymerization of Tetrathiafulvalene-Based Electrode Materials, A. Yoshimura, K. Hemmi, H. Moriwaki, R. Sakakibara, H. Kimura, Y. Aso, N. Kinoshita, R. Suizu, T. Shirahata, M. Yao, K. Awaga, H. Yorimitsu, Y. Misaki, ACS Appl. Mater. Interfaces, 14, 35978-35984 (2022).

・26. Synthesis, Structure and Properties of Donor-Acceptor-Type [4]Dendralenes, Y. Matsumoto, R. Matsuda, A. Yoshimura, T. Shirahata, Y. Misaki, Chem. Lett. 51, 581-584 (2022).

・25. Synthesis and Properties of Fused Extended Tetrathiafulvalene Donors with Dithienylmethylene Spacer and Application to Organic Rechargeable Batteries, T. Yamauchi, T. Kubo, A. Fujioka, A. Yoshimura, T. Shirahata, H. Miyamoto, M. Yao, Y. Misaki, Bull. Chem. Soc. Jpn. 94, 1940-1947 (2021).

・24. SYNTHESIS AND PROERTIES OF FUSED TRIAD DONORS COMPOSED OF TWO 1,3-DITHIOLE[5]RADIALENES AND EXTENDED TETRATHIAFULVALENE, K. Kagawa, T. Higashi, A. Yoshimura, Y. Misaki, HeteroCycles, 102, 961-970 (2021).

・23. p-Conjugated Molecules Containing Tetrathiafulvalene and Benzo[b]phosphole Oxide: Synthesis, Structure, and Electrochemical and Optical Properties, S. Ikeda , A. Yoshimura, T. Shirahata, Y. Matano, Y. Misaki, Chem. Lett. 50, 1581-1585 (2021).

・22. A Tris-fused Tetrathiafulvalene Analog Composed of an Anthraquinoid- and Two Vinyl-extended Tetrathiafulvalenes, T. Oshima, A. Sasaki, T. Yamauchi, A. Yoshimura, T. Shirahata, M. Yao, Y. Misaki, Chem. Lett. 50, 1164-1168 (2021).

・21. Synthesis, Structures, and Electrochemical Properties of Bis- and Tetrakis-(diphenylphosphino)tetrathiafulvalenes Extended with an Anthraquinoid Spacer, A. Yoshimura, K. Henmi, A. Handa, K. Kagawa, T. Shirahata, Y. Misaki, Eur. J. Org. Chem. 2021, 1960-1963 (2021).

・20. Synthesis, Structure, and Electrochemical Properties of Extended Tetrathiafulvalene Dimers Linked by Flexible Butylene Chain, Y. Kawasaki, R. Sakakibara, M. Fujisaki, M. Yamashita, A. Yoshimura, T. Shirahata, M. Yao, Y. Misaki, Bull. Chem. Soc. Jpn. 94, 1059-1065 (2021).

・19. Donor-Acceptor Triads Composed of Tetrathiafulvalene and Benzoquinone Fused by Benzene Spacers: Application to the Positive Electrode Materials for Use in Rechargeable Batteries, T. Yamauchi, W. Hirabayashi, A. Yoshimura, M. Yao, Y. Misaki, Bull. Chem. Soc. Jpn. 94, 44-52 (2021).

・18. Synthesis of Peripherally Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C-H Arylation and Construction of a Double-Helical Cobalt-Based Metal-Organic Framework, A. Yoshimura, K. Henmi, H. Kimura, R. Sakakibara, R. Ochi, T. Shirahata, H. Yorimitsu, Y. Misaki, Synthesis 53, 326-331 (2021).

・17. Synthesis and Properties of Tetrathiafulvalenes Bearing 6-Aryl-1,4-dithiafulvenes, A. Yoshimura, H. Kimura, K. Kagawa, M. Yoshioka, T. Itou, D. Vasu, T. Shirahata, H. Yorimitsu, Y. Misaki, Beilstein J. Org. Chem. 16, 974-981 (2020).

・16. Fused Tetrathiafulvalene and Benzoquinone Triads: Organic Positive-Electrode Materials Based on a Dual Redox System, Y. Misaki, S. Noda, M. Kato, T. Yamauchi, T. Oshima, A. Yoshimura, T. Shirahata, M. Yao, ChemSusChem, 13, 2312-2320 (2020).

・15. Synthesis, structures, and electrochemical and optical properties of phosphinine derivatives functionalized tetrathiafulvalene analogs, A. Yoshimura, H. Kimura, A. Handa, N. Hashimoto, M. Yano, S. Mori, T. Shirahata, M. Hayashi, Y. Misaki, Tetrahedron Lett. 61, 151724 (2020).

・14. Synthesis and Properties of [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidenes and Dicyanomethylidene and Application to Rechargeable Batteries, T. Yamauchi, Y. Shibata, T. Aki, A. Yoshimura, M. Yao, Y. Misaki, Chem. Lett. 47, 1176-1179 (2018).

・13. Radical hydrophosphorylation of alkynes with R₂P(O)H generating alkenylphosphine oxides: scope and limitations, T. Huang, Y. Saga, H. Guo, A. Yoshimura, A. Ogawa, L.-B. Han, J. Org. Chem. 83, 8743-8749 (2018).

・12. A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons, A. Yoshimura, M. Yoshinaga, H. Yamashita, M. Igarashi, S. Shimada, K. Sato, Chem. Commun. 53, 5822-5825 (2017).

・11. Air-induced double addition of P(O)-H bonds to alkynes: a clean and practical method for the preparation of 1,2-bisphosphorylethanes, H. Guo, A. Yoshimura*, T. Chen, Y. Saga, L.-B. Han, Green Chem. 19, 1502-1506 (2017).

・10. Highly Selective Photoinduced Perfluoroalkylation of Vinylsilanes and Its Application to Synthesis of Water-Shedding Polysilanes, A. Yoshimura, A. Nomoto, M. Uchida, H. Kusano, T. Saeki, A. Ogawa, Res. Chem. Intermed. 43, 3433-3443 (2017).

・9. An Efficient Base-catalyzed Double Addition of H-phosphine Oxides to Alkynes, A. Yoshimura, Y. Saga, Y. Sato, A. Ogawa, T. Chen, L.-B. Han, Tetrahedron Lett. 57, 3382-3384 (2016).

・8. Photoinduced Metal-free Diboration of Alkynes in the Presence of Organophosphine Catalysts, A. Yoshimura, Y. Takamachi, K. Mihara, T. Saeki, S. Kawaguchi, L.-B. Han, A. Nomoto, A. Ogawa, Tetrahedron, 72, 7832-7838 (2016).

・7. Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light, A. Yoshimura, Y. Takamachi, L.-B. Han, A. Ogawa, Chem. Eur. J. 21, 13930-13933 (2015).

・6. Photoinduced Synthesis of P-perfluoroalkylated Phosphines from Triarylphosphines and Their Application in the Copper-Free Cross-Coupling of Acid Chlorides and Terminal Alkynes, S. Kawaguchi, Y. Minamida, T. Okuda, Y. Sato, T. Saeki, A. Yoshimura, A. Nomoto, A. Ogawa, Adv. Synth. Catal. 357, 2509-2519 (2015).

・5. Pinacol Couplings of a Series of Aldehydes and Ketones with SmI₂/Sm/Me₃SiCl in DME, A. Yoshimura, T. Saeki, A. Nomoto, A. Ogawa, Tetrahedron, 71, 5347-5355 (2015).

・4. Photoinduced Reductive Coupling of Organochlorosilanes with SmI₂/Sm, A. Yoshimura, Y. Tomisaka, Z. Li, A. Nomoto, A. Ogawa, Heteroat. Chem. 25, 684-689 (2014).

・3. Rhodium-Catalyzed Hydrothiolation of Alkynes with Thiols for Construction of Sulfur-Containing π-Conjugated Systems, A. Yoshimura, A. Nomoto, A. Ogawa, Res. Chem. Intermed. 40, 2381-2389 (2014).

・2. Novel Reducing Properties of a Series of Lanthanoid Metals in the Presence of SmI₂, Y. Tomisaka, A. Yoshimura, A. Nomoto, M. Sonoda, A. Ogawa, Res. Chem. Intermed. 39, 43-38 (2013).

・1. New Entry to the Construction of Si-Si Linkages : Sm/SmI₂-Induced Efficient Reductive Coupling of Organochlorosilanes, Z. Li, K. Iida, Y. Tomisaka, A. Yoshimura, T. Hirao, A. Nomoto, A. Ogawa, Organometallics, 26, 1212-1216 (2007).

Other Publications

・8. Recent advances in developing tetrathiafulvalene analogs of electrode materials: Discovery of an in-cell polymerization technique, A. Yoshimura, Y. Misaki, Pure Appl. Chem. 95, 431-438 (2023).

・7. 高いサイクル特性を示すリチウムイオン二次電池用有機正極活物質, 吉村 彩, 御崎 洋二, 化学工業2022年11月号, 665-668 (2022).

・6. サイクル寿命の向上を指向した新規リチウムイオン二次電池用有機正極活物質の開発, 吉村 彩, 御崎 洋二, 月間JETI 2022年6月号, 13-15 (2022).

・5. 新規リチウムイオン二次電池用有機正極活物質の開発, 吉村 彩, 御崎 洋二, 月間「クリーンエネルギー」2022年1月号, 32-35 (2022).

・4. Periphery Modification of Tetrathiafulvalenes: Recent Development and Applications, A. Yoshimura, Y. Misaki, Chem. Rec. 21, 3520-3531 (2021).

・3. Catalytic C-H Arylation of Tetrathiafulvalenes for the Synthesis of Functional Materials, H. Yorimitsu, A. Yoshimura, Y. Misaki, Synthesis, 52, 3326-3336 (2020).

・2. 有機リン化合物, 韓 立彪, 吉村 彩, リンの事典, 大竹 久夫, 18-19 (2017).

・1. Activation Procedures of SmI₂ and Its Utilization for Organic Reactions, A. Yoshimura, A. Ogawa, Samarium: Chemical Properties, Occurrence and Potential Applications, Ed. K. D. Danford, Nova Science Publishers, 47-98 (2014).