お知らせ

日時：2022年12月22日（木）16:00～17:30

場所：大阪公立大学 杉本キャンパス 理学部会議室

講師：Prof. Rory Waterman (米国バーモント大学化学科)

演題：Advances in Catalytic Hydrophosphination

概要：A family of earth abundant, highly active, and selective catalysts have been discovered and investigated with photolysis being a critical factor in activity. The arc of catalysis moves from zirconium to iron chemistry that informs most recent discoveries in simple copper catalysts, like Cu(acac)2, that may be the most active known. At ambient temperature with irradiation centered at 365 nm, conversions with Cu(acac)2 are remarkable with some reactions complete in minutes. The photocatalysis is hypothesized to proceed by excitation to a low-lying orbital with M–P antibonding character, weaking that bond to avail faster insertion.

連絡先： 大阪公立大学理学研究科  森内敏之・板崎真澄（内線 2915 or 3213）