PUBLICATIONS 論文
PUBLICATIONS論文
2025
Enantioselective Synthesis of Chiral Ferrocenyl Aminoalcohols: Simultaneous Induction of Multiple Types of Chirality by a Rhodium-Catalyzed Asymmetric Ring-Opening Strategy
Isoda, T.; Jimba, K.; Kawashima, K.; Nishinoiri, T.; Mori, S.; Tsurusaki, A.; Kamikawa, K.

Benzo-Fused Phosphepines: Synthesis by Gold(I)-Catalyzed Intramolecular Hydroarylation and Ring Inversion
Tsurusaki, A.; Kishimoto, M.; Komura, A.; Ura, R.; Kamikawa, K.

2024
Diphosphene with a phosphineborane tether and its rhodium complex
Tsurusaki, A.; Takechi, S.; Kamikawa, K.

2023
Synthesis and Properties of Optically Active [7]Helicene-Fused Oxanorbornene Polymers by Ring-Opening Metathesis
Fujikata, K.; Gon, M.; Tanaka, K.; Chujo, Y.; Tsurusaki, A.; Kamikawa, K.

Asymmetric reactions involving aryne intermediates Nat. Rev. Chem. 2023,
Kamikawa, K.

Rh(I)-Catalyzed Enantioselective Arylation of Cyclic N-Sulfonyl Diketimines Using Planar-Chiral Phosphine-Olefin Ligands Based on a (Cyclopentadienyl)manganese(I) Scaffold with a Highly Fluorinated Aryl Phosphino Group J. Org. Chem. 2023,
Shimamoto, R.; Tsurusaki, A.; Kamikawa, K.

Synthesis, Structures, and Properties of p-Extened Phosphindolizine Derivatives Chem. Eur. J. 2023,
Tsurusaki, A.; Tahara, S.; Nakamura, M.; Matsumoto, H.; Kamikawa, K.

2022
Palladium(ii) complexes of bis(diphosphene) with different coordination behaviors
Ura, R.; Tsurusaki, A.; Kamikawa, K.

2021
Multiple Helicenes Featuring Synthetic Approaches and Molecular Structures
Tsurusaki, A.; Kamikawa, K.
Chem. Lett. 2021, 50, 1913−1932, https://doi.org/10.1246/cl.210409
Selected as an inside cover picture.

Transformation from triple helicene to double helicene embedding adjacent stereogenic carbon atoms and axial stereogenicity
Yubuta, A.; Tsurusaki, A.; Kamikawa, K.
Chem. Commun. 2021, 57, 6600−6603, https://doi.org/10.1039/D1CC02393D
Selected as a back cover picture.

Gold(I)-Catalyzed Intramolecular Hydroarylation of o-Ethynylarylphosphonium Salt Leading to the Formation of Seven- and Six-membered Phosphacycles
Tsurusaki, A.; Shimatani, H.; Kamikawa, K.
Asian. J. Org. Chem. 2021, 10, 154-159. DOI: 10.1002/ajoc.202000669

2020
Assembly of [5]Helicene Subnits by Palldium-Catalyzed Reactions:Syntehsis, Sturectures, and Theoretical Study of Multiple Helicenes
Hosokawa, T.; Tsurusaki, A.; Kamikawa, K.

Synthesis, Structure, and Complexation of an S-Shaped Double Azahelicene with Inner-Edge Nitrogen Atoms
Kawashima, T.; Matsumoto, Y.; Sato, T.; Yamada, Y. M. A.; Kono, C.; Tsurusaki, A.; Kamikawa, K.
Chem. Eur. J. 2020, 26, 13170-13176. DOI: org/10.1002/chem.202002405
Selected as a front cover picture.

Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution
Yubuta, A.; Hosokawa, T.; Gon, M.; Tanaka, K.; Chujo, Y.; Tsurusaki, A.; Kamikawa, K.
J. Am. Chem. Soc. 2020, 142, 10025-10033. DOI: org/10.1021/jacs.0c01723
Selected as a supplementary cover picture.

Theoretical Examination of the Plausible Reaction Process for Stereoselective Synthesis of Hexapole Helicene via a Palladium-Catalyzed [2 + 2 + 2] Cyclotrimerization of [5]Helicenyl Aryne
Hosokawa, T.; Asadaa, T.; Kamikawa, K.
J. Phys. Chem. A 2020, 124, 652-661. DOI: org/10.1021/acs.jpca.9b09533

A Gold(I) Complex with a 1,1′-Binaphthyl-Substituted Diphosphene: Synthesis, Structure, and Catalytic Application to Intramolecular Hydroarylation Reactions
Tsurusaki, A.; Ura, R.; Kamikawa, K.
Organometallics 2020, 39, 87-92. DOI: org/10.1021/acs.organomet.9b00665

2019
Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers
Tsurusaki, A.; Matsumoto, H.; Kamikawa, K.

Theoretical Investigations of Rh-Catalyzed Asymmetric 1,4-Addition to Enones using Planar-Chiral Phosphine-Olefin Ligands
Kawashima, K.; Sato, T.; Ogasawara, M.; Kamikawa, K.; Mori, S.

2018
Synthesis of Substituted Helicenes by Ir-Catalyzed Annulative Coupling of Biarylcarboxylic Acid Chlorides with Alkynes
Kamikawa, K.; Den, H.; Tsurusaki, A.; Nagata, T.; Miura, M.

1,1’-Binaphthyl-substituted Diphosphene: Synthesis, Structures, and Chiral Optical Properties
Tsurusaki, A.; Ura, R.; Kamikawa, K.

2017
Molybdenum-Catalyzed Enantioselective Synthesis of Planar-Chiral (5h-Phosphacyclopentadienyl)manganese(I) Complexes and Application in Asymmetric Catalysis
Ogasawara, M.; Tseng, Y.-Y.; Uryu, M.; Ohya, N.; Chang, N.; Ishimoto, H.; Arae, S.; Takahashi, T.; Kamikawa, K.

Syntehsis, Structures, and Properties of Hexapole Helicenes: Assembling Six [5]Helicene Substructures into Highly Twisted Aromatic Systems
Hosokawa, T.; Takahashi, Y.; Matsushima, T.; Watanabe, S.; Kikkawa, S.; Azumaya, I.; Tsurusaki, A.; Kamikawa, K.
J. Am. Chem. Soc. 2017, 139, 18512-18521.
Selected as a front cover picture. Highlighted in "Chemistry World", "JACS Sphotlights" and 「化学工業日報」

Eficient Synthesis of Polycyclic g-Lactoams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates
Hoshimoto, Y.; Ashida, K.; Sasaoka, Y.; Kumar, R.; Kamikawa, K.; Verdaguer, X.; Riera, A.; Ohashi, M.; Ogoshi, S.

Kinetic Resolution of Planar-Chiral (h5-Bromocyclopentaddenyl)manganese(I) Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis
Ogasawara, M.; Tseng, Y.-Y.; Liu, Q.; Chang, N.; Yang, X.; Takahashi, T.; Kamikawa, K.

Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganeses (I) Scaffold to Achieve High Enantioselectivity
Kamikawa, K.; Tseng, Y.-Y.; Jisn, J.-H.; Takahashi, T.; Ogasawara, M.

Synthesis of N-Aryl Carbazoles by a Palladium-Catalyzed Direct C-H Arylation of 2-N,N- (Diarylamino)phenyl Triflates
Uwa, K.; Tseng, Y.-Y.; Kamikawa, K.

2016
Stereoselective Synthesis of N-Arylindoles and Related Compounds with Axially Chiral N-C Bonds
Kinoshita, S..; Kamikawa, K.
Tetrahedron Symposium in Print (Special Issue for Axial Chirality) 2016, 72, 5202-5207.

2015
Ring-Closing Metathesis of (hapto5-Alkenylcyclopentadienyl)(alkenylphophine)manganese(I) Dicarbonyl Complexes
Tseng, Y-Y.; Kamikawa, K.; Qian, W.; Takahashi, T.; Ogasawara, M.

Simultaneous Indution of Axial and Planar Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis
Kamikawa, K.; Arae S.; Wu, W.-Y.; Nakamura C.; Takahashi, T.; Ogasawara, M.

Synthesis of Double Helicene by a Palladium-Catalyzed Cross-Coupling Reaction: Structure and Pysical Properties
Kashihara, H.; Asada, T.; Kamikawa, K.

2014
Phosphine-Olefin Ligands Based on a Planar-Chiral (pai-Arene)chromium Scaffold: Design, Synthesis, and Appication in Asymmetric Catalysis
Ogasawara, M.; Tseng, Y.-Y.; Arae, S.; Morita. T.; Nakaya, T.; Wu, W. Y.; Takahashi, T.; Kamikawa, K.


暮らしの中のクロムから有機合成反応まで
神川 憲
化学と教育, 2014, 62, 300.
2013
Synthesis of Azahelicene N-Oxide by Palladium Catalyzed Direct C-H Annulation of the Pendant Z-Bromovinyl Side
Kaneko, E.; Matsumoto, Y..; Kamikawa, K.
Chem. : -Eur. J. 2013, 19. 11837-11841
[Selected as the Journal Front Cover]
[Highlighed in SYNFACTS 2013]
[Highlighted in WILEY-VCH, Hot topics]

2012
Cheimsitry of Dynamic hapto6-(Arene)chromium Complexes
Wu, W.-Y. ; Kamikawa, K.
Bull. Jpn. Soc. Coord. Chem. 2012, 60, 24-31s
Kinetic Resolution of Planar-Chiral (h6-Arene)chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis
Ogasawara, M.; Wu, W.-Y. Arae, S.; T.; Watanabe, S.; Morita, Takahashi, T.; Kamikawa, K.

2011
Ring-closing metathesis within chromium-coordination sphere: facile access to phosphine-chelate (pai-arene)chromium complex
Ogasawara, M.; Wu, W.-Y. Arae, S.; Morita, T.; Watanabe, S.; Takahashi, T.; Kamikawa, K.

2010
Induction of Axially Chiral N-C Bond in N-Aryl Acridane by Stereoselective Chromium Tricarbonyl Migration planar-axial-helical chirality relay
Mori, A.; Kinoshita, S.; Furusyo, M.; Kamikawa, K.

Molecular Design of Small Organic Molecules Based on Structural Infomation for a Confomationally Constrained Peptide that Binds to G-CSF Receptor
El-Haggar, R.; Kamikawa, K.; Machi, K.; Ye, Z.; Ishino, Y.; Tsumuraya, Fujii, I.

2009
Synthesis of Organocatalysts with One-handed Helix and Their Application to the Kinetic Resolution of Secondary Alcohol
Kamikawa, K.; Shiromoto, T.; Yamaguchi, J. Takemoto, S.; Matsuzaka, H.
Res. Chem. Intermed. 2009, 35, 931-937 (invited paper)
Induction of one-handed helical oligo(p-benzammide)s by domino effect based on planar-axial-helical chirality relay
Kamikawa, K.; Fukumoto, K.; Yoshihara, K.; Furusyo, M.; Uemura, M.; Takemoto, S.; Matsuzaka, H.
